By Louis D. Quin
An authoritative and entire advent to organophosphorus chemistry The vast, fascinating box of organophosphorus chemistry has grown drastically during the last few many years, with a wealth of possibilities for study and purposes improvement. A consultant to Organophosphorus Chemistry deals chemists in academia and whole, up to date insurance of the basics with a watch on destiny advancements during this region. the world over famous authority Louis D. Quin extends his skilled viewpoint and perception at the subject by:* Surveying an important phosphorus-containing useful teams* together with consultant tools of synthesis, plus references to particular artificial strategies* Outlining advances in stereochemical features of phosphorus chemistry* overlaying parts of present study, corresponding to strange coordination states, heterocycles, functions of 31P-NMR, and different spectroscopic tools* offering a number of references to special assessment articles and up to date literature* proposing digital mechanisms and reactive intermediates the place demonstrated* Discussing the significance of phosphorus compounds in residing structures and in agricultural applicationsLiberally illustrated with equations and structural formulation, A consultant to Organophosphorus Chemistry provides a nearly exceptional creation to the subject material, making it an essential educational instrument for aspiring chemists and practising chemists alike.
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Extra info for A Guide to Organophosphorus Chemistry
The similarity to the problem of the phosphoryl group should be apparent. 10,11,13 To the organic chemist, however, the chemistry of ylides is quite definitely that of a species with a strong carbanionic character, easily seen in the Wittig reaction with a carbonyl compound (Eq. 9). This reaction is discussed in greater detail in chapter 11. In most literature, the ylide structure alone is shown, and this will be done here. It must be remembered, however, that what makes the ylide stable is the secondary interaction between the carbanionic center and positive phosphorus, making the PC bond short and strong.
Some Major Uses of Organophosphorus Compounds as Reagents in Organic Synthesis 379 References 384 Index 387 Page ix Preface Organophosphorus chemistry is a very broad and exciting field, with many opportunities for research or applications development. This book is my personal reflection, from my 50 years of experience, on the fundamentals of the field and to some extent on where future development might take place. It is written as a survey to aid the student or practicing chemist with little prior exposure to the field, for I know how difficult it is for "beginners" to get a grasp on its fundamentals.
Quin. p. cm. Includes index. Organophosphorous compounds. Title. 07-dc21 99-43429 Printed in the United States of America. A. Organization of Compounds by the Bonding to Phosphorus 8 2 B. C. D. E. F. G. H. I. J. K. L. M. 1. A. B. C. D. 1. A. Phosphine Oxides 95 4 B. C. D. 1. A. B. C. D. E. F. 1. A. B. C. D. E. F. G. H. I. J. K. A. B. C. D. E. A. B. C. A. B. C. D. E. A. B. C. D. E. A. B. C. D. E. F. Some Major Uses of Organophosphorus Compounds as Reagents in Organic Synthesis 379 References 384 Index 387 Page ix Preface Organophosphorus chemistry is a very broad and exciting field, with many opportunities for research or applications development.
A Guide to Organophosphorus Chemistry by Louis D. Quin