By R. J. Cremlyn
Sulfur chemistry is turning into more and more vital because the function of this point is explored in either organic and environmental fields. After the preliminary chapters have mentioned the synthesis, reactivity, and homes of the compounds usually, all the subsequent 9 chapters takes a particular sulfur containing sensible crew and expands the dialogue on man made methods. the ultimate bankruptcy seems on the significant makes use of of organo-sulfur compounds and their influence on organic and environmental parts.
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Additional resources for An Introduction to Organosulfur Chemistry
2. P. Page, Organosulfur Chemistry-Synthetic Aspects, Academic Press, London, 1995. 3. Organic Chemistry of Sulfur (Ed. S. Oae), Plenum Press, New York, 1977. 4. M. G. Veronkov, N. S. Vyazankin, E. N. Deryagina, A. S. Nakhmanovich and V. A. Usov, in Reactions of Organic Compounds with Sulfur (Ed. J. S. Pizey), Consultants Bureau, New York, 1987. 5. H. Cerfontain, Mechanistic Aspects in Aromatic Sulfonation and Desulfonation, Part 1, Electrophilic Aromatic Sulfonation and Related Reactions, Interscience, New York, 1967.
Such selective monodecarboxylation is characteristic of the effect of heating a malonic acid derivative. 4 The first step in determination of the primary structure of a polypeptide involves breaking the disulfide bridges by oxidation with performic acid and separating the resultant sulfonic acids (Scheme 25). Two important examples of proteins containing disulfide bridges are the hormones insulin and vasopressin. Insulin is used in the treatment of diabetes owing to its ability to control glucose metabolism.
Scheme 50 can be modified to provide a useful synthesis of unsymmetrical tetrasulfides like (82); in this case, sulfur monochloride is condensed with the appropriate thiol and 2-mercaptoethanol (78) (Scheme 52) Scheme 51 Scheme 52 Examination of a series ofsulfides of type ArSnCH2CH2OH (n = 1–4) showed that the monosulfides (n = 1) and disulfides (n = 2) were stable at room temperature for one year, but the trisulfides (n = 3) and tetrasulfides (n = 4) were not stable under these conditions and decomposed to mixtures of products.
An Introduction to Organosulfur Chemistry by R. J. Cremlyn